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Issue 06/2020

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  • Renewable
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Highlights: Films / Flexibles Bioplastics from waste-streams Basics: Eutrophication

Materials A new

Materials A new packaging solution for aerosols B reak free of the design and performance constraints of aluminium and steel. Next generation (partly biobased) plastics can provide the perfect solution for personal care and household products. In 2019, the global aerosol market was valued at USD86 billion, and it is estimated to see compound annual growth in revenue of 6.6% over the next seven years, largely within the personal care sector [1]. Aluminium and steel dominate in aerosol packaging, but what about plastic? New polymers offer compelling attractions when it comes to design flexibility, core performance and environmental impact. Poly(ethylene-co-isosorbide) terephthalate (PEIT), a modified form of polyethylene terephthalate (PET) containing isosorbide, a renewable feedstock for high performance materials, offers exciting possibilities for aerosol packaging and is just beginning to penetrate the market. Why switch from metal to plastic? The use of plastic packaging for aerosols is growing, and there are good starch reasons why it should. A switch to plastic addresses primary limitations such as corrosion, weight, design flexibility, or safety (risk of explosion due to over-pressure) When it comes to manufacturing efficiency and economics, plastic can also be highly competitive with lower costs and the possibility of just-in-time production, adjacent to the filling line. In Europe, the Aerosol Dispensing Directive (ADD) [2] currently limits the volume of plastic aerosols to 220 ml, but these guidelines were written in 1975 and are due to be updated in 2020. Advances in plastics increase the likelihood of a substantial revision with modern materials well-suited to the demands of aerosol packaging. What is PEIT? PEIT is a semi-aromatic copolyester closely similar to PET. PET is the world’s most used polymer, particularly for packaging and synthetic fibers, and is the preferred packaging material for aerosols. Indeed, a collaborative special industry group established by Petcore Europe and the European Aerosols Association (FEA) is already focusing on how best to handle an anticipated rise in PET aerosols in the household waste stream over coming years [3]. PET recycling – both mechanical and chemical – is well-established. PET is a copolymer of ethylene glycol and terephthalic acid. The manufacture of PEIT additionally incorporates isosorbide as a third monomer via the bulk polymerisation of ethylene glycol, terephthalic acid, and isosorbide. While ethylene glycol and terephthalic acid are still mainly from petrochemicals, isosorbide is a plant derived monomer, produced from annually renewable feedstocks. Plant-based starches are hydrolyzed to glucose that is converted to sorbitol, which is converted to isosorbide by hydrogenation (see below illustration). glucose sorbitol Over the last couple of decades, companies such as Roquette (Lestrem, France), the global leader in isosorbide production and supply, have refined isosorbide processing technology to the point of industrial-scale manufacture. Roquette operates the world’s first industrial scale plant supplying material of unsurpassed quality and stability. Sustainable, non-toxic and available in different grades, with one tailored specifically to the requirements of the polyester market, the resulting isosorbide has a very low carbon footprint of just 0.09 kg CO 2 /kg of product (as shown in an Internal comparative study based on life cycle analysis methodology, peer-reviewed by an external auditor). In summary, incorporating isosorbide into PET improves the environmental credentials of virgin polyester. Equally exciting is the potential isosorbide offers to enhance PET properties. How are its properties different from PET? Isosorbide is non-toxic, nNon-endocrine disruptor and available at very high (>99.5 %) purity. These characteristics make it suitable for food, cosmetics/ personal care, and pharmaceutical applications. PEIT is a glass-like, heat-resistant, hot-fillable copolyester that can be used as either a recyclable or reusable plastic within these sectors. It offers: • High gloss • Good optical properties • High impact resistance • Enhanced chemical resistance. isosorbide 42 bioplastics MAGAZINE [06/20] Vol. 15

Materials However, the key characteristics driving interest in PEIT for aerosol packaging include a high glass transition temperature, Tg, and compatibility with existing PET recycling practices. A higher glass transition temperature… High purity isosorbide increases the glass transition temperature, T g , of speciality copolyesters more effectively than alternative diols [CBDO - 2,2,4,4-Tetramethyl-1,3-cyclobutanediol, SPG – Spiroglycol, and CHDM – Cyclohexanedimethanol]. High purity isosorbide increases the glass transition temperature, Tg, of speciality copolyesters more effectively than alternative diols [CBDO - 2,2,4,4-Tetramethyl-1,3-cyclobutanediol, SPG – Spiroglycol, and CHDM – Cyclohexanedimethanol]. The T g of a polymer is a critical parameter since it defines the temperature above which the thermal properties of the material begin to change and more rubbery behavior establishes; below their Tg, polymers are more glass-like. An important limitation of PET as an aerosol packaging material is that it does not have the thermal resistance required to meet the criteria laid out in FEA Standard 647 [4]. The incorporation of isosorbide directly addresses this limitation by increasing T g . It is more effective that any other alternative diol in this regard as well as being the only bio-based molecule. “The ability of isosorbide to increase the T g of PET is critical for this application and it is more effective than any other replacement diol in this regard. Unlike PET, PEIT meets the thermal resistance requirements laid out in the FEA standards for aerosols - a major gain,” says René Saint-Loup, Performance Materials and Cosmetic ingredients Technical Team Manager, Roquette …with no loss of recyclability Semi-crystalline PEIT meets the T g specification for aerosol packaging and can be mechanically recycled into existing PET streams. Meeting a T g of ~90 °C, as required for aerosol packaging, requires less than 15 % isosorbide incorporation, i.e., the substitution of less than 15 % of the ethylene glycol in conventional PET. This means that the resulting PEIT is semicrystalline and can be mechanically recycled with existing PET waste streams. Recycled materials containing up to 50 % modified PET fulfill all the European PET Bottle Platform (EPBP) Testing Protocols for assessing PET recycling Semi-crystalline PEIT meets the Tg specification for aerosol packaging and can be mechanically recycled into existing PET streams. compatibility [5]. PEIT can also carry the Resin Identification Code #1, as reserved for PET, based on the requirements of ASTM Standard 7611-7611M (Standard Practice for Coding Plastic Manufactured Articles for Resin Identification) [6]. Looking ahead Commercial products from companies such as Plastipak, Alpla and Airopack showcase the multiple benefits of switching from metal to PET aerosol packaging and illustrate what is already available. Lighter, lower cost, and with a reduced carbon footprint, these solutions point to a bright future for plastic aerosols. Easily recycled through existing waste streams, they also offer distinctive features such as transparency. PEIT has the potential to further enhance the plastic aerosol product portfolio by providing better technical performance, notably a higher T g , with no loss of recyclability. For those looking to exploit the growing demands for plastic aerosols, isosorbide is a high performance monomer that demands a closer look. MT References [1] Aerosol Market Size, Share & Trends Analysis Report By Application (Personal Care, Household, Automotive & Industrial, Foods, Paints), By Material, By Type, By region, And Segment Forecasts, 2020 – 2027. https:// [2] Directive 75/324/EEC – aerosol dispensers. Available to read at: https:// [3] Plastic Aerosol Recycling Special Industry Group. groups/plastic-aerosol-recycling-special-industrygroup.html [4] FEA Standard 647: Plastic Aerosol Dispensers – Technical Requirements. Available to download at: and-fea-650-are-now-available/ [5] “How we do a Recycling Evaluation !” [6] ASTM D7611/D7611M – 20 Standard Practice for Coding Plastic Manufactured Articles for Resin Identification. Details and available to purchase: bioplastics MAGAZINE [06/20] Vol. 15 43

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