Recycling Upcycling
Recycling Upcycling process for post-consumer PLA waste Designed for performance and durability, plastics have become an indispensable part of everyday life. However, poor waste management has led to the accumulation of plastic in the environment. In order to solve this issue, the European Union has embarked on a transition to a circular system in which plastics are reused, repaired and recycled plastics. It also aims to produce plastics that are made from renewable resources (bio-based plastics). Polylactic acid (PLA) is one of the most promising and frequently used polyesters in this category. Flexible and versatile, PLA is used in applications ranging from disposable cutlery and degradable sutures to rigid packaging and extrusion coatings, although the dominant market for PLA is food packaging. A biobased alternative to fossil-based plastics the production of PLA is both raw material and energy-intensive (2.39 kg corn cobs, 50 kg water and 54 MJ of fossil energy are required to produce one-kilogram PLA). While a potential high-volume raw material, infrastructure is as yet lacking for separately collecting and recycling PLA. Therefore, it often ends up in other conventional waste streams, thereby contaminating them and disturbing the state-of-the-art municipal recycling strategies. Six Fraunhofer institutes (Fraunhofer ICT, Fraunhofer UMSICHT, Fraunhofer LBF, Fraunhofer IML, Fraunhofer IAP and Fraunhofer IVV) are exploring ways for sustainable transformation of the entire plastic value chain to a circular economy. Researchers at Fraunhofer ICT along with Fraunhofer LBF have developed a strategy to chemically recycle postconsumer PLA waste into a lactate ester (ethyl lactate) which finds its commercial applications in chemical synthesis, magnetic tape coatings, plastic, metal, wood and food industry. The process represents an economically and environmentally sustainable recycling strategy, capable of nearly completely depolymerizing the PLA substrate along with a high yield of ethyl lactate (80 %) in a relatively short period of time (< 20 min) and under mild reaction conditions (< 70 °C, ambient pressure). An outstanding feature of this system is the use of a conventional and commercialized eco-friendly, organic catalyst. Another special feature of this process is the use of an eco-friendly, low-boiling solvent, capable of selectively dissolving the PLA fraction from a mixed plastic waste stream, consisting mainly of PET and PP. This flexible process scheme is capable of handling virgin PLA of different grades (Total Corbion LX175 and NatureWorks PLA 6032 D) as well as post-consumer PLA cups. The process has been scaled up in 2019 from a laboratory scale to a technical scale (15 L) and its robustness was demonstrated by recycling post-consumer waste PLA cups, without any effect on the yield of the lactate ester. The production of both PET and PLA is expected to increase by 2021, with the percentage increase of PLA being higher than that of PET. Due to its application, the estimated maximum contamination of PLA in waste PET streams could vary between 0.8 % to 8 % by 2021. In such a scenario, innovative methods for removal of PLA would be required in order to assure high-quality recycled PET. In addition, the huge demand for PLA on the consumer market, coupled with high feedstock and energy demands for its production, is a major concern for the manufacturers of PLA. In this situation, implementing the aforementioned strategy will not only completely utilize the valuable polyhydroxy acid even after the end of its conventional life cycle but will also add value to the supply chain. With this strategy, adaptation of a circular economy approach for the synthesis of virgin-PLA would lead to approximately 50 % energy savings compared to the conventional PLA production processes, starting from corn-cobs as feedstock. The present concept therefore has the potential to solve the problems at the confluence of chemical recycling of PLA and sustainable production of lactate esters (potential alternative to conventional petrochemical solvents) by strictly abiding to the fundamentals of green chemistry. It moreover sets up the foundation for a “circular bioeconomy” and benefits both “circular economy” of conventional plastics and different elements across the entire societal value chain. MT www.ict.fraunhofer.de 46 bioplastics MAGAZINE [05/20] Vol. 15
Material News Toray launches new, environmentallyfriendly nylon COMPEO Toray Industries, Inc. has developed a new, more sustainable nylon that represents a major step forward in the company’s sustainability vision. The nylon is the latest addition to the company’s integrated Ecodear brand for biomass-based polymer materials and products. Toray’s new Ecodear nylon is 60% bio-based, based on sebacic acid derived from castor beans. The resulting fibre, initially available in 10, 20 and 50 denier versions, can be spun using the same process as conventional nylon. In setting up the integrated brand, Toray aimed to advance Toray’s ambition to provide solutions to environmental issues by expanding its business of biomass-based polymer materials and products using the ecodear brand in wideranging fields of fiber, resin and film. The development of Ecodear nylon demonstrates the benefits of Toray’s vertically integrated structure. As a chemical manufacturer and a textile company, Toray can maintain control over the product quality, from the creation of polymers to the production of finished yarns. Ecodear nylon can be used to make bio-based versions of proven Toray brand technologies like Dermizax and Entrant. Toray’s development and launch of new bio-based textile technologies such as Ecodear nylon, and its continued progress with recycled materials allow the company to reduce the amount of petroleum used in the fabric production supply chain, as well as carbon dioxide emissions - both of which are vital goals detailed in the company’s Sustainability Vision. Toray plans to market the textile in fall 2020, targeting the active outdoor sports and skiing markets, as well as athleisure. www.toray.com Leading compounding technology for heat- and shear-sensitive plastics Castor oil plant Petroleum Biobased sebacic acid Hexamethylene diamine Approx 60% Polymerization Approx 40% Biobased N610 q Spinning Approx. 60 % Biobased Filament yarns Uniquely efficient. Incredibly versatile. Amazingly flexible. With its new COMPEO Kneader series, BUSS continues to offer continuous compounding solutions that set the standard for heat- and shear-sensitive applications, in all industries, including for biopolymers. • Moderate, uniform shear rates • Extremely low temperature profile • Efficient injection of liquid components • Precise temperature control • High filler loadings www.busscorp.com bioplastics MAGAZINE [05/20] Vol. 15 47
